MaTecK GmbH
   
www.MaTecK.com
 
 
 
Last Update
1st July 2007
 


Lead single crystal 82Pb207.19

Known to ancient civilizations.

  [Anglo-Saxon: lead; Latin: plumbum]
  French: plomb
  German: blei
  Italian: piombo
  Spanish: plomo

Description: Lead is a soft, weak, ductile, dull grey metal that tarnishes in moist air but is stable to oxygen and water. It dissolves in HNO3. Lead is used in batteries, cables, glass, solder, radiation shielding, etc. A little is still used in paints and petrol but generally this use is being phased out.


Metal single crystal properties
State: single crystal  
Crystal structure: fcc  
Production method: Bridgman  
Standard size: diameter 10-12mm
thickness 1-2mm
 
Orientation: (100), (110) and (111)  
Orientation accuracy: <2°, <1°, <0.5° or <0.1°  
Polishing: electrochemical  
Roughness of surface: <0.03µm  
Purity: 99.99%  
Typical analysis (ppm): Ag < 0,5
Bi < 5

Cu < 0,5
Fe < 1
Pb balance


Further Materials properties
Crystal structure: (cell dimensions/pm), space group
f.c.c. (a=495.00), Fm3m
X-ray diffractions mass absorption coefficients: CuKa 232 (µ/r) / cm2g-1
MoKa 120 (µ/r) / cm2g-1
Neutron scattering length: 0.9405 b/10-12 cm
Thermal neutron capture cross-section: 0.171 sa / barns
Density: 11.4 g/cm3  
Melting point: 327.50 °C / 600.65 °K
Boiling point: 1739.85 °C / 2013 °K
Molar volume: 18.26 cm3
Thermal conductivity: 35.3 [300 K] Wm-1K-1
Coefficient of linear thermal expansion: 29.1 x 10-6 K-1
Electrical resistivity: 20.648x10-8 [293 K] Wm
Mass magnetic susceptibility: -1.39 x 10-9(s) kg-1m3
Young's modulus: 16.1 GPa
Rigidity modulus: 5.59 GPa
Bulk modulus: 45.8 GPa
Poisson's ratio: 0.44 GPa
Radii: Pb4+ 84; Pb2+ 132; atomic 175; covalent 154
Electronegativity: 2.33 (Pauling); 1.55 (Allred); 3.90 eV (absolute)
Effective nuclear charge: 5.65 (Slater); 12.39 (Clementi); 15.33 (Froese-Fischer)
Number of Isotopes (incl. nuclear isomers): 41
Issotope mass range: 184 -> 214


Biological data
Biological role: none
Toxicity  
Toxic intake: c. 50 mg - 100 g
Lethal intake: LD50 (acetate, intravenous, mouse)=104 mg kg-1
Hazards: Lead is moderately toxic by ingestion and affects the gut and central nervous system and causes anaemia. However, most ingested lead passes through the body without being absorbed. It is a cumulative poison and lead poisoning is a common occupational disease. Lead compounds can be carcinogenic and teratogenic
Level in humans  
Blood: 0.21 mg dm-3
Bone: 3.6 - 30 p.p.m.
Liver: 3 - 12 p.p.m.
Muscle: 0.23 - 3.3 p.p.m.
Daily dietary intake : 0.06 - 0.5 mg
Total mass of element in average
[70 kg] person:
120 mg (stored in skeleton)


Geological data
Minerals:  
 Mineral  Formula  Density  Hardness  Crystal apperance
 Anglesite  PbSO4  6.38  2.5 - 3  orth., adam./greasy white
 Boulangerite  Pb5Sb4S11  6.23  2.5 - 3  orth., met. bluish-grey
 Bournonite  PbCuSbS3  5.8  2.5 - 3  orth., met. steel-grey
 Cerussite  PbCO3  6.55  3 - 3.5  orth., adam./vit. Col.
 Galena  PbS  7.58  2.6  cub., met. grey
 Minium  Pb3O4  9.05  2.5  tet., greasy red/brown
 Pyromorphite  Pb5(PO4)3Cl  7.04  3.5 - 4  hex., barrel-shaped crystals, often hollow
Chief ore: galena is the main ore (with silver as a by-product), pyromorphite, boulangerite and cerussite are minor ores.
World production: 2.8 x 106 tonnes/year
Main mining areas: galena in USA, Australia, Mexico, West Germany; boulangerite in France.
Reserves: 85 x 106 tonnes
Specimen: available as foil, granules, ingots, powder, rod, shot and wire. CARE !
Abundances  
Sun: 85.1 (relative to H = 1 x 1012)
Earth's crust: 14 p.p.m.
Atmosphere: (volume) trace
Seawater:  
  Atlantic surface: 30 x 10-6 p.p.m.
  Atlantic deep: 4.0 x 10-6 p.p.m.
  Pacific surface: 10 x 10-6 p.p.m.
  Pacific deep: 1 x 10-6 p.p.m.
Residence time:: 50 years
Classification: scavenged
Oxidation state: II

Other sizes and specifications on request


© 1996 - 2008 MaTecK GmbH - Im Langenbroich 20 - D-52428 Juelich - phone: +49 (0) 2461 / 9352-0 - fax: +49 (0) 2461 / 9352-11 - Contact: info@mateck.de