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Last Update
1st July 2007
 


Terbium 65Tb158.924


Discovered in 1843 by C.G. Mosander at Stockholm, Sweden.

  [Named after Ytterby, Sweden]
  French: terbium
  German: Terbium
  Italian: terbio
  Spanish: terbio

Description: Terbium is a silvery metal, and a particularly rare member of the so-called rare earth group (more correctly termed the lanthanides). It is slowly oxidised by air and reacts with cold water. Terbium is used in solid state devices and lasers.


Materials properties
Density: 8829 kg/m-3 [293 K]
Melting point: 1629 °K
Boiling point: 3396 °K
Molar volume: 19.31 cm3
Thermal conductivity: 11.1 [300 K] Wm-1K-1
Coefficient of linear thermal expansion: 7.0 x 10-6 K-1
Electrical resistivity: 114 x 10-8 [298 K] Wm
Mass magnetic susceptibility: +1.15 x 10-5(s) kg-1m3
Young's modulus: 55.7 GPa
Rigidity modulus: 22.1 GPa
Bulk modulus: 38.7 GPa
Poisson's ratio: 0.261 GPa
Radii: Tb4+ 81; Tb3+ 97; atomic 178; covalent 159
Electronegativity: n.a. (Pauling); 1.10 (Allred); ≤ 3.2 eV (absolute)
Effective nuclear charge: 2.85 (Slater); 8.30 (Clementi); 11.39 (Froese-Fischer)
Number of Isotopes (incl. nuclear isomers): 31
Issotope mass range: 145 -> 165


Biological data
Biological role: None.
Toxicity  
Toxic intake: n.a.
Lethal intake: LD 50 (chloride, oral, mouse)= > 5100 mg kg -1
Hazards: Terbium is mildly toxic by ingestion, and is a skin and eye irritant.
Level in humans  
Organs: n.a. but low
Daily dietary intake : n.a.
Total mass of element in average [70 kg] person: n.a. but very low


Crystal data
Crystal structure, (cell dimentions / pm), space group Tb orthorhombic (a=359, b=626, c=571.5), Cmcm

α-Tb h.c.p. (a = 360.10, c=569.36), P63/mmc

β-Tb b.c.c. (a=402), Im3m

T(α -> orthorhombic) = 220 K; T(α -> β) = 1590 K

X-ray diffraction: mass absorption coefficients (µ/ρ)/cm2g-1 : CuKα 273 MoKα 67.5
Neutron scattering length, b/10-12cm: 0.738
Thermal neutron capture cross-section, σa/barns : 23.4


Geological data
 Mineral  Formula  Density  Hardness  Crystal apperance
 Monazite*  (Ce,La,Nd,Th,etc.)PO4  5.20  5 - 5.5  mon., waxy/vit. yellow-brown
*Although not a major constituent, terbium is present in extractable amounts.

Chief ore: monazite
World production: c. 10 tonnes/year
Main mining areas: USA, Brazil, India, Sri Lanka, Australia
Reserves: c. 3 x 105 tonnes
Specimen: available as chips or ingots. Safe. Terbium powders is very irritating to skin and eyes. Care!
Abundances  
Sun: n.a.
Earth's crust: 1.1 p.p.m.
Seawater:  
  Atlantic surface: 1 x 10-7 p.p.m.
  Atlantic deep: 1.5 x 10-7 p.p.m.
  Pacific surface: 0.8 x 10-7 p.p.m.
  Pacific deep: 2.5 x 10-7 p.p.m.
Residence time: n.a.
Classification: recycled
Oxidation state: III

Other sizes and specifications on request


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