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1st July 2007
 


Rubidium 37Rb85.47


Discovered in 1861 by R.W. Bunsen and G. Kirchhoff at the University of Heidelberg, Germany.

  [Latin: rubidius = deepest red]
  French: rubidium
  German: Rubidium
  Italian: rubidio
  Spanish: rubidio

Description: Rubidium is a soft, white, metal which is silvery when first cut but it oxidises rapidly in air and ignites. It reacts violently with water. Rubidium is obtained by the reaction of calcium or potassium metal with rubidium chloride. The metal and its compounds are rarely used commercially, and only a little is used for research purposes.


Materials properties
Density: 1532 kg/m-3 [293 K]; 1475 [liquid at m.p.]
Melting point: 312.2 °K
Boiling point: 961 °K
Molar volume: 55.79 cm3
Thermal conductivity: 58.2 [300 K] Wm-1K-1
Coefficient of linear thermal expansion: 90 x 10-6 K-1
Electrical resistivity: 12.5 x 10-8 [293 K] Wm
Mass magnetic susceptibility: +2.49 x 10-9(s) kg-1m3
Young's modulus: 2.35 GPa
Rigidity modulus: 0.91 GPa
Bulk modulus: n.a.
Poisson's ratio: 0.30 GPa
Radii: Rb+ 149; atomic 247.5; van der Waals 244
Electronegativity: 0.82 (Pauling); 0.89 (Allred); 2.34 eV (absolute)
Effective nuclear charge: 2.20 (Slater); 4.98 (Clementi); 6.66 (Froese-Fischer)
Number of Isotopes (incl. nuclear isomers): 30
Issotope mass range: 75 -> 98


Biological data
Biological role: Rubidium has no known role; its salts have a stimulatory effect.
Toxicity  
Toxic intake: can be toxic by ingestion
Lethal intake: LD50 (chloride, oral, mouse) = 3800 mg kg-1
Hazards: Rubidium salts are generally inert, and their toxicity is almost always that of the anion, not of the Rb+. However, in the body, rubidium substitutes for potassium and too much can be dangerous.

Level in humans  
Blood: 2.49 mg dm-3
Bone: 0.1 - 5 p.p.m.
Liver: 20 - 70 p.p.m.
Muscle: 20 - 70 p.p.m.
Daily dietary intake : 1.5 - 6 mg
Total mass of element in average [70 kg] person: 680 mg


Crystal data
Crystal structure, (cell dimentions / pm), space group b.c.c. (a = 562), Im3m
X-ray diffraction: mass absorption coefficients (µ/ρ)/cm2g-1 : CuKα 117 MoKα 90.0
Neutron scattering length, b/10-12cm: 0.709
Thermal neutron capture cross-section, σa/barns : 0.38


Geological data
 Minerals: No minerals as such are known, but rubidium is present in significant amounts in lepidolite (see lithium, pollucite (see caesium) and carnallite (see potassium).
World production: n.a.
Reserves: n.a.
Specimen: available as ingots in sealed ampoules. Danger!
Abundances  
Sun: 400 (relative to H = 1 x 1023)
Earth's crust: 90 p.p.m.
Seawater: 0.12 p.p.m.
Residence time: 800 000 years
Classification: accumulating
Oxidation state: I

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